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Originally published February 6 2006

Scientists in North Carolina reach important mark in the development of spray-on polymer solar cells

by Mike Adams, the Health Ranger, NaturalNews Editor

Professor David Caroll of Wake Forest University has announced that his team of researchers has hit a mark of six percent efficiency with spray-on polymer solar cells.



Researchers in the US have improved the efficiency of a 'spray-on' polymer-based solar cell which moves it closer to practical use. The North Carolina scientists have hit six per cent efficiency in buckyball-doped polymer solar cells. "We have developed a photovoltaic which is flexible and has a high efficiency," Professor David Carroll... ... of Wake Forest University told Electronics Weekly. "It is just like paint, you just paint it on," said Carroll. High efficiency is a relative term, Carroll pointed out. His cells are close to six per cent efficient: double that of similar cells, but low-cost glass substrate amorphous silicon cells achieve 12 per cent. Starting with a flexible polycarbonate substrate, Wake Forest sputters on ITO (indium tin oxide), spins on the active layer, then tops it off by depositing a thin metal contact. "The electrons leave through the metal and the holes leave through the ITO," said Carroll. This thing can be rolled up and taken anywhere you want." Electron-hole separation in the Wake Forest cells occurs in a polymer layer doped with a fullerene - a compound including C60 buckyballs. There is no junction as such in this kind of cell, instead C60 acts as an electron-acceptor through the bulk of the polymer layer, splitting up photon-induced excitons. Crucial to the increase in efficiency at Wake Forest is a novel heat treatment. "We flash-anneal this device by putting a temperature gradient across the material," said Carroll. "The nano-phase material begins to form elongated crystals. We get nano-material 0.8nm across, but in a structure hundreds of nanometres across." Research teams across the globe are working on C60-doped solar cells. In particular two University of California campuses: Santa Barbara and UCLA, are in friendly rivalry with Carroll.


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